CobaltMaghrebV1, Main, Exploration, bibRecord, 000484

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate

Identifieur interne : 000484 ( Main/Exploration ); précédent : 000483; suivant : 000485

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate

Auteurs : Thameur Sahbani [Tunisie] ; Wajda Smirani Sta [Tunisie] ; Salem S. Al-Deyab [Arabie saoudite] ; Mohamed Rzaigui [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3212155

Abstract

In the title compound, (C₅H₁₄N₂)[Co(H₂O)₆]₂(SO₄)₃, the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H₂O)₆]²⁺ and [C₅H₁₄N₂]²⁺. The [Co(H₂O)₆]²⁺ cations form unconnected octahedra. Sulfate anions intercalated between cationic species connect them via N—H⋯O and O—H⋯O hydrogen bonds and electrostatic interactions.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212155

DOI: 10.1107/S1600536811027012
PubMed: 22090857
PubMed Central: 3212155

Affiliations:

Arabie saoudite, Tunisie

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<front><div type="abstract" xml:lang="en"><p>In the title compound, (C<sub>5</sub>
H<sub>14</sub>
N<sub>2</sub>
)[Co(H<sub>2</sub>
O)<sub>6</sub>
]<sub>2</sub>
(SO<sub>4</sub>
)<sub>3</sub>
, the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H<sub>2</sub>
O)<sub>6</sub>
]<sup>2+</sup>
 and [C<sub>5</sub>
H<sub>14</sub>
N<sub>2</sub>
]<sup>2+</sup>
. The [Co(H<sub>2</sub>
O)<sub>6</sub>
]<sup>2+</sup>
 cations form unconnected octahedra. Sulfate anions intercalated between cationic species connect them <italic>via</italic>
 N—H⋯O and O—H⋯O hydrogen bonds and electrostatic interactions.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate

Source :

Abstract

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Serveur d'exploration sur le cobalt au Maghreb

Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate

Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate

Source :

Abstract

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Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate

Homopiperazine-1,4-diium bis[hexaaquacobalt(II)] trisulfate